Archean greenstone belts are a vital window into the tectonostratigraphic processes that operated in the early Earth and the geodynamics that drove them. However, the majority of greenstone belts worldwide are highly-deformed, complicating geodynamic interpretations. The volcano-sedimentary sequence of the 2775-2690 Ma Fortescue Group is different in that it is largely undeformed, offering a unique insight into the architecture of greenstone sequences. In the Fortescue magmatic rocks, geochemical signatures that in deformed belts in the Superior or Yilgarn Cratons might have been interpreted as arc-like, are explained by contamination of rift-related mantle and plume-derived magmas with Pilbara basement crust; understanding the wider geological and structural setting allows a more complete interpretation. However, contamination of Fortescue magmas by an enriched sub-continental mantle lithosphere (SCLM) is an alternative hypothesis to the crustal contamination model. If demonstrated, the addition of sediments and fluids to the SCLM, required to form enriched/metasomatised SCLM, would suggest active subduction prior to the Neoarchean. To test this hypothesis, we collected Hf-O isotopic data on zircons from felsic volcanic rocks throughout the Fortescue Group; if the contamination had a subducted sedimentary component (δ18O>20‰), then the O-isotopes should record a heavy signature. The results show that the ca. 2775 Ma Mt Roe Formation has εHfi from 0 to -5.6, and δ18OVSMOW of +4.8- +0.3‰, with the majority of values <+3‰. The ca. 2765 Ma Hardey Formation (mostly sediments) has highly unradiogenic εHfi of -5 to -9.4, and δ18O of +7.8- +6.6‰. The ca. 2730 Ma Boongal Formation displays similar values as for Mt Roe, with εHfi +1.9 to -5.5 and δ18O +3.0 to -0.6‰. The ca. 2720 Ma Tumbiana Formation shows the greatest range in εHfi from +4.9 to -4.6, with δ18O +7.1- +0.7‰, with the majority between +4.5 and +2.5‰. Data from the 2715 Ma Maddina Formation are more restricted, with εHfi between +4.0 and -0.1, and δ18O +5.0- +3.8‰. The youngest formation, the 2680 Ma Jeerinah Formation, has εHfi +2.3 to -6.2, and δ18O +5.1 to -2.1‰. Importantly, these data provide little evidence of a cryptic enriched SCLM source in the Fortescue magmas. Furthermore, the dataset contains some of the lightest δ18O data known for Archean zircon, highlighting a ca. 100 Myr period of high-temperature magma-water interaction, with long-term continental emergence implied by the trend to meteoric δ18O compositions. The exception to this is the Hardey Formation, which may have formed via crustal anatexis in a period of reduced heat-flow between the 2775-2665 and 2730-2680 Ma events. Data from the other formations show a broad trend of increasing δ18O and εHf from 2775 to 2680 Ma. We suggest this represents the effects of progressive cratonic rifting, allowing mantle-derived magmas to reach the surface less impeded, and also a decreasing role of meteoric water in the rift zone as the sea invades. As a result, the εHf and δ18O data from the Fortescue Group represent the evolving nature of an Archean rift zone, from an emergent volcanic centre, to a submarine environment.